Possibility of Metal Accumulation in Reed Canary Grass (Phalaris arundinacea L.) in the Aquatic Environment of South-Western Polish Rivers.

A four-year research study was conducted on aquatic plants (reed canary grass) growing in the beds of three rivers and their tributaries in Lower Silesia, Poland. Metal contents (Cu, Cd, Ni, Pb, Zn, Fe, Mn) were determined in plant samples, metal accumulation in water (BCFw) and sediment (BCFB), Metal Pollution Index (MPI) and Enrichment Factor (EF) were calculated. The highest contents of copper, lead, nickel and cadmium were found in reed canary grass sampled from the Nysa Szalona River. The highest values were recorded for zinc in the Bystrzyca River, and for iron and manganese in the Strzegomka River. The series of metals were as follows: Nysa Szalona and Strzegomka: Cd < Ni < Pb < Cu < Zn < Mn < Fe, Bystrzyca: Cd < Ni < Cu < Pb < Zn < Mn < Fe. Throughout the study period, the lowest values of metals in plants were recorded in 2015 and 2018, and the highest in 2017. The general picture of MPI in aquatic plants is arranged in the series Bystrzyca < Strzegomka < Nysa Szalona. These values classify the studied material at a high level of pollution in all rivers. In the comparison of the two extreme sites, i.e., source−mouth, higher values were found at the mouth of the reservoir, which suggests that metals move with the water current and accumulate more with the direction of the river flow, which is most likely a consequence of the influence of the catchment area as the source of metals. The series of EF enrichment factor values were as follows: Bystrzyca­Ni < Cd < Fe < Cu < Zn < Mn < Pb, Nysa Szalona­Ni < Fe < Zn < Cd < Mn < Cu < Pb, Strzegomka­Ni < Cd < Fe < Zn < Cu < Pb < Mn. For all the samples studied, the values found in spring were much higher than in autumn, which indicates the great importance for research in that area. The levels of copper and iron were within the range of moderate values, lead and manganese reached very high and exceptionally high values, and the remaining metals were within the values described as significant. Bioaccumulation of metals determined relative to bottom sediments was highest in 2017 and lowest in 2018, while bioaccumulation relative to water was highest in 2018 and lowest in 2016. The four-year study found that the metal content in reed canary grass was mostly within the range of mean values presented in the literature from moderately polluted areas. Also, no significant deviation was found from levels that have been recorded for the same rivers for more than two decades.

Quality Evaluation Indices for Soybean Oil in Relation to Cultivar, Application of N Fertiliser and Seed Inoculation with Bradyrhizobium japonicum.

Soybean ranks second in production and consumption of vegetable oils worldwide and these are expected to continue to increase. The suitability of soybean oil for specific uses is determined by the fatty acid composition from which a number of indices and indicators can be calculated. The aim of this study was to evaluate the indices of nutritional and health-promoting fat in seeds of soybean cultivars grown in 2016-2019 under the influence of varying doses of N and inoculation with Bradyrhizobium japonicum. Omega 3 and Omega 6, unsaturated fatty acids (UFA), saturated fatty acids (SFA), polyunsaturated fatty acids (PUFA), index of desirable fatty acids (DFA), sum of hypercholesterolemic fatty acids (OFA), index of atherogenicity (AI), index of thrombogenicity (TI), oleic desaturation ratio (ODR), linoleic desaturation ratio (LDR), calculated oxidizability value (COX) and the hypocholesterolemic/hypercholesterolemic ratio (HH), saturation fat index (S/P) and ALA/LA, OL/(LA+ALA) ratios and the consumer index (CI) were included. Fat quality indices for soybean seeds were strongly determined by weather conditions. Seeds of the cv. Aldana contained higher amounts of Omega 6 and featured more favourable MUFA/PUFA and OL/(LA+ALA) ratios, while the seeds of the cv. Annushka had more favourable CI and higher ODR, COX and S/P indices. No important differences were observed regarding the effect of nitrogen dose and seed inoculation on the formation of the DFA, OFA, HH, AI, TI and CI indices. The value of the S/P index suggests that higher nitrogen rates (60 kg∙ha-1) and the lack of inoculation treatment produce seeds with a more favourable dietary fatty acid balance.

Aluminum in Bottom Sediments of the Lower Silesian Rivers Supplying Dam Reservoirs vs. Selected Chemical Parameters.

The study was carried out on sediments collected from three rivers: Nysa Szalona, Strzegomka and Bystrzyca flowing in southwestern Poland. The content of Al in sediments and in bottom water was determined in relation to chemical conditions. The study was carried out in a four-year cycle, during spring and autumn. The aim of the study was to determine the level and accumulation of aluminum in sediments of rivers supplying dam reservoirs storing water for consumption. The sediments studied were mineral in nature, with neutral pH and moderate sulfate content. The level of Al and heavy metals in the sediments was the highest in the Nysa Szalona River and the lowest in the Strzegomka River, which was also evident in the concentration factor (CF). In terms of season, higher Al contents were recorded in sediments in autumn than in spring, which was also reflected in the concentration factor (CF). Along the course of the river, a gradual decrease in Al levels was observed in successive tributaries in the Nysa Szalona and Strzegomka Rivers, while there was no apparent regularity for the Bystrzyca. Against this background, a comparison of extreme sites below the springs and at the reservoir outlet shows that values were higher in the Nysa Szalona below the springs, and lower in the Strzegomka and Bystrzyca below the reservoir outlet. The general picture of Al and heavy metal loading of the studied sediments shows the lowest loading for the Strzegomka, only the enrichment factor (EF) was the lowest for the Nysa Szalona: metal pollution index (MPI)-S < B < NS, contamination factor (Cf)-S < B < NS, degree of contamination (DC)-S < NS < B, EF-NS < B < S, geoaccumulation index (Igeo)-S < B < NS, CF-S < NS < B. There was no effect of catchment size and river length on Al levels in sediments.